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Joint Rotational Analysis of 24 Bands of the H2Se Molecule
1Department of Chemical Physics, University of Science and Technology of China, Hefei, 230026, People's Republic of China
Journal of Molecular Spectroscopy
|May 8, 1998
Abstract:
A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 x 10(-3) cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13(+); 1)/(13(-); 1) and (06(+); 0)/(06(-); 0) could be analyzed; the results are discussed. Copyright 1998 Academic Press.