Faraday Laser Magnetic Resonance Spectroscopy of Vibrationally Excited C2D

We studied the gas phase spectrum of the deuterated ethynyl radical C2D in the region between 3196 and 3243 cm-1 using a Faraday LMR spectrometer in combination with a CO overtone laser. The C2D radicals were generated in a dc glow discharge containing helium, deuterium, and acetylene. We observed a hot band between two vibronic 2Pi states with an origin at 3225 cm-1. The lower level is assigned to the first excited bending level of the electronic X ground state. The upper level corresponds to the first excited electronic state A at 3513 cm-1, which was observed previously [J. Mol. Struct. 190, 41-60 (1988)]. This region is subject to strong vibronic interaction, caused by mixing of the electronic X ground state with the A state at 3513 cm-1. From the analysis of the spectra we could determine the orbital g factor of the upper level, which gave important information about the mixing ratios. In addition we were able to derive a precise term value for the first excited bending level of the electronic X ground state. The experimentally derived molecular parameters are compared with theoretically calculated values, obtained by ab initio calculations. Copyright 1998 Academic Press.