Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Two-dimensional nuclear-Zeeman-resolved electron spin echo envelope modulation (NZ-ESEEM) spectroscopy

M Willer1, J Granwehr, J Forrer

  • 1Laboratorium für Physikalische Chemie, Eidgenössische Technische Hochschule, Zürich, CH-8092, Switzerland.

Journal of Magnetic Resonance (San Diego, Calif. : 1997)
|July 9, 1998
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Mapping proton and carbon dioxide electrocatalytic reductions at a Rh complex by <i>in situ</i> spectroelectrochemical NMR.

Chemical science·2025
Same author

Establishing grassland mixtures on mine wastes - a two-year mesocosm study.

International journal of phytoremediation·2024
Same author

Impact of an evidence-based intervention on urinary catheter utilization, associated process indicators, and infectious and non-infectious outcomes.

The Journal of hospital infection·2020
Same author

Experimental evidence for the relaxation coupling of all longitudinal <sup>7</sup>Li magnetization orders in the superionic conductor Li<sub>10</sub>GeP<sub>2</sub>S<sub>12</sub>.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2019
Same author

Chemical shift reference scale for Li solid state NMR derived by first-principles DFT calculations.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2018
Same author

Investigation of the Li-ion conduction behavior in the Li<sub>10</sub>GeP<sub>2</sub>S<sub>12</sub> solid electrolyte by two-dimensional T<sub>1</sub>-spin alignment echo correlation NMR.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2018
Same journal

Localization-driven exchange contrast in diffusion exchange spectroscopy.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2026
Same journal

4.5 Tesla superconducting miniature magnet in liquid nitrogen.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2026
Same journal

Folding and unfolding dynamics of a DNA aptamer studied by heteronuclear <sup>1</sup>H-<sup>13</sup>C correlation zz-exchange spectroscopy.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2026
Same journal

Multi-spin control from one-spin pulses.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2026
Same journal

Altering MRI rotating frame relaxations by changing the truncation level of Hyperbolic Secant pulse.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2026
Same journal

Effects of proton exchange on the lifetimes of long-lived states in aliphatic chains.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2026
See all related articles

A new nuclear-Zeeman-resolved electron spin echo envelope modulation (ESEEM) method correlates nuclear transition and Zeeman frequencies. This technique enhances electron paramagnetic resonance spectroscopy by analyzing magnetic field interactions with nuclear spins.

Area of Science:

  • Electron Paramagnetic Resonance (EPR) Spectroscopy
  • Pulsed EPR Techniques
  • Solid-State Chemistry

Background:

  • Electron spin echo envelope modulation (ESEEM) is a powerful pulsed EPR technique.
  • Correlating nuclear and electron spin properties is crucial for understanding molecular and material structures.
  • Existing ESEEM methods have limitations in resolving specific nuclear interactions.

Purpose of the Study:

  • To introduce a novel two-dimensional ESEEM experiment, nuclear-Zeeman-resolved ESEEM (NZ-ESEEM).
  • To demonstrate the capability of NZ-ESEEM in correlating nuclear transition frequencies with nuclear Zeeman frequencies.
  • To present the instrumentation and application examples of the new method.

Main Methods:

  • Development of a three-pulse ESEEM sequence.

Related Experiment Videos

  • Incorporation of a magnetic field pulse during the free evolution period.
  • Analysis of the resulting spectral data to resolve nuclear transition and Zeeman frequencies.

    • Main Results:

    • Successful implementation of the nuclear-Zeeman-resolved ESEEM (NZ-ESEEM) experiment.
    • Demonstration of the correlation between nuclear transition frequencies and nuclear Zeeman frequencies.
    • Validation of the method's capacity through two distinct application examples.

    Conclusions:

    • NZ-ESEEM offers enhanced resolution for studying nuclear spin interactions in EPR.
    • The method provides a new tool for detailed structural and dynamic investigations.
    • This technique expands the capabilities of pulsed EPR spectroscopy.