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Isolation and structure revision of pepluane diterpenoids from euphorbia peplus

Hohmann1, G nther G, Vasas

  • 1Department of Pharmacognosy, Albert Szent-Gyorgyi Medical University, P.O. Box 121, H-6701 Szeged, Department of Pharmaceutical Analysis, Albert Szent-Gyorgyi Medical University, 4 Somogyi u., H-6720 Szeged, Hungary, and Instit.

Journal of Natural Products
|January 23, 1999
PubMed

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Structure of Conjugated Dienes01:16

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Introduction
Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...