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Thermodynamics of Micellization of Surfactants of Low Aggregation Number: The Aggregation of Propranolol

Mosquera1, Ruso, Attwood

  • 1Departamento de Física Aplicada y Departamento de Física de la Materia Condensada, Facultad de Física, Universidad de Santiago de Compostela, E-15706 Santiago de Compostela, Spain

Journal of Colloid and Interface Science
|January 30, 1999
PubMed

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Surfactants, named for their behavior at interfaces, positively adsorb at the interfaces of two phases, reducing interfacial tension. Their versatility as emulsifiers, detergents, and foaming agents stems from this ability. Surfactants, often termed amphiphiles, share the property of amphipathy, with molecules having both hydrophilic and hydrophobic portions. The hydrophilic part is called the head, and the hydrophobic part, including an elongated alkyl substituent, forms the tail.Surfactants...
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Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...
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