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ACS Omega|August 29, 2019
Synthesis of Trimetallic (HPd@M2Au8)3+ Superatoms (M = Ag, Cu) via Hydride-Mediated Regioselective Doping to (Pd@Au8)2Haru Hirai, Shinjiro Takano, Tatsuya Tsukuda
Journal of the American Chemical Society|June 21, 2018
Hydride-Doped Gold Superatom (Au9H)2+: Synthesis, Structure, and TransformationShinjiro Takano, Haru Hirai, Satoru Muramatsu, et al.
Journal of the American Chemical Society|September 5, 2018
Hydride-Mediated Controlled Growth of a Bimetallic (Pd@Au8)2+ Superatom to a Hydride-Doped (HPd@Au10)3+ SuperatomShinjiro Takano, Haru Hirai, Satoru Muramatsu, et al.
Inorganic Chemistry|June 12, 2020
Understanding Doping Effects on Electronic Structures of Gold Superatoms: A Case Study of Diphosphine-Protected M@Au12 (M = Au, Pt, Ir)Haru Hirai, Shinjiro Takano, Toshikazu Nakamura, et al.
Chemical Science|June 7, 2021
Ligand-protected gold/silver superatoms: current status and emerging trendsHaru Hirai, Shun Ito, Shinjiro Takano, et al.
Nano Letters|July 30, 2025
Programmed Assembly of IrAu12 Nanoclusters into Dimers and Trimers: Electron Microscopy Observation and Spectroscopic CharacterizationYuto Fukumoto, Shinjiro Takano, Yosuke Asami, et al.
Nanoscale|January 13, 2026
Effects of phosphine ligand denticity on catalytic activity and durability of gold nanoparticles in the oxidation of benzyl alcoholYiwei Wu, Shinya Masuda, Kosuke Sakamoto, et al.
Angewandte Chemie (International Ed. in English)|February 9, 2024
Diphosphine-Protected IrAu12 Superatom with Open Site(s): Synthesis and Programmed Stepwise AssemblyYuto Fukumoto, Tsubasa Omoda, Haru Hirai, et al.
JACS Au|July 30, 2026
Programming Structural Flexibility for Tunable Gas Sorption via Hydrogen Bonding in Polyoxometalate-Based Porous Ionic CrystalsShunsuke Mochizuki, Haru Hirai, Tomochika Kasagiri, et al.
Angewandte Chemie (International Ed. in English)|May 24, 2022
Doping-Mediated Energy-Level Engineering of M@Au12 Superatoms (M=Pd, Pt, Rh, Ir) for Efficient Photoluminescence and PhotocatalysisHaru Hirai, Shinjiro Takano, Takuya Nakashima, et al.
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