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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Ionic Crystal Structures02:42

Ionic Crystal Structures

14.6K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Alkyl Halides02:45

Alkyl Halides

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Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

43.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Video Experimental Relacionado

Updated: Aug 15, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

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Cadros de haluros conductores superiónicos habilitados por haluros unidos a la interfaz

Jiamin Fu1,2, Shuo Wang3, Jianwen Liang1

  • 1Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9, Canada.

Journal of the American Chemical Society
|December 30, 2022
PubMed
Resumen
Este resumen es generado por máquina.

Los investigadores descubrieron nuevos marcos de haluros similares a la zeolita para electrolitos en estado sólido. Estos materiales exhiben una rápida conducción de iones de litio, allanando el camino para las avanzadas baterías de estado sólido.

Área de la Ciencia:

  • Ciencias de los materiales
  • La electroquímica
  • Química del estado sólido

Sus antecedentes:

  • Los haluros ternales (Li-M-X) son electrolitos de estado sólido (SSE) prometedores para baterías de estado sólido debido a la compatibilidad del cátodo y la conductividad iónica.
  • Las SSE de haluros superiónicos existentes a menudo presentan octaedros [MCl6] con vías de difusión de Li+ asistidas por tetraedros.

Objetivo del estudio:

  • Introducir una nueva clase de estructuras de haluros similares a la zeolita para mejorar el rendimiento de los electrolitos en estado sólido.
  • Investigar la conductividad iónica y los mecanismos de difusión de Li+ en estas nuevas estructuras halogenadas.

Principales métodos:

  • Simulaciones de dinámica molecular para verificar la difusión de Li+.
  • Injerto de especies halogenadas en estructuras de SmCl3 para crear iones móviles.

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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  • Mediciones de la conductividad iónica a 30 °C.
  • Principales resultados:

    • Se informó de una nueva clase de estructuras de haluros similares a la zeolita, ejemplificada por SmCl3, con canales 1D y prismas trigonales [SmCl9]6.
    • La difusión rápida de Li+ con una corta distancia de salto de 2,08 Å fue confirmada a través de simulaciones.
    • Se logró una conductividad iónica superior a 10-4 S cm-1 a 30 °C utilizando LiCl como adsorbente.

    Conclusiones:

    • Las estructuras de haluros similares a la zeolita ofrecen un nuevo motivo estructural para los conductores superiónicos.
    • La conductividad iónica de los compuestos MCl3 / haluro se correlaciona con la conductividad del haluro injertado, la unión interfacial y las propiedades del marco.
    • Esta investigación amplía los principios de diseño de las SSE basadas en haluros y promueve la innovación en el desarrollo de conductores superiónicos.