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相关概念视频

Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.9K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.9K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.6K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.6K
Alkyl Halides02:45

Alkyl Halides

17.1K
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
17.1K
Ionic Bonds00:42

Ionic Bonds

118.8K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.8K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

43.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
43.7K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

27.1K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
27.1K

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相关实验视频

Updated: Aug 15, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.1K

通过接口结合的化物实现的超声波导电

Jiamin Fu1,2, Shuo Wang3, Jianwen Liang1

  • 1Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9, Canada.

Journal of the American Chemical Society
|December 30, 2022
PubMed
概括
此摘要是机器生成的。

研究人员发现了固态电解质的新化物结构. 这些材料具有快速的离子导电,为先进的固态电池铺平了道路.

科学领域:

  • 材料科学
  • 电化学
  • 固态化学

背景情况:

  • 由于阴极兼容性和离子导电性,三极化物 (Li-M-X) 是固态电解质 (SSE) 的有希望的固态电池.
  • 现有的超离子化物SSE通常具有四面体辅助Li+扩散通路的[MCl6]八面体.

研究的目的:

  • 为提高固态电解质性能引入一种新型的化物框架.
  • 研究这些新的化物结构中的离子导电性和Li+扩散机制.

主要方法:

  • 初始分子动力学模拟以验证Li+扩散.
  • 将化物种移植到SmCl3框架上以创建移动离子.
  • 在30°C测量离子导电性.

主要成果:

  • 报告了一种新的化物框架类型,以SmCl3为例,具有1D通道和[SmCl9]6-三角镜.
  • 通过模拟证实了2.08 Å的短跳距离的快速Li+扩散.
  • 使用LiCl作为吸附剂在30°C时达到超过10-4 S cm-1的离子导电性.

结论:

  • 这种化物框架为超离子导体提供了一个新的结构动机.
  • MCl3/化物复合材料的离子导电性与移植化物导电性,界面结合性和框架性质相关.

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

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Last Updated: Aug 15, 2025

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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  • 这项研究扩展了基于化物的SSE的设计原则,并促进了超声波导体开发的创新.