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Geometría, potencial de reducción y energía de reorganización del sitio binuclear Cu(A), estudiado por la teoría

M H Olsson1, U Ryde

  • 1Contribution from the Department of Theoretical Chemistry, Lund University, Chemical Centre, P.O. Box 124, S-221 00 Lund, Sweden.

Journal of the American Chemical Society
|August 9, 2001
PubMed
Resumen

El sitio dimérico de cobre (A) en las proteínas muestra flexibilidad estructural, con dos estados de energía casi iguales en el estado de valencia mixta. Esta flexibilidad permite un pequeño cambio en el potencial de reducción, lo que afecta la transferencia de electrones en las enzimas.

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