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Un catalizador mejorado para la arilación asimétrica de enolados cetónicos

Takayuki Hamada1, André Chieffi, Jens Ahman

  • 1Contribution from the Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139.

Journal of the American Chemical Society
|February 14, 2002
PubMed
Resumen

Un nuevo catalizador de paladio permite la alfa-ariación enantioselectiva de cetonas a temperatura ambiente. Este sistema eficiente crea centros estereogénicos cuaternarios con alto rendimiento y excelente enantioselectividad, avanzando la síntesis asimétrica.

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