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Reacciones de cicloadición de acrilonitrilo en la superficie de Si(100)-2 x 1

Cheol Ho Choi1, Mark S Gordon

  • 1Department of Chemistry, College of Natural Sciences, Kyungpook National University, Taegu 702-701, South Korea. cchoi@knu.ac.kr

Journal of the American Chemical Society
|May 23, 2002
PubMed
Resumen

Los métodos mecánicos cuánticos revelan que las reacciones de acrilonitrilo en las superficies Si{100}-2x1 ocurren a través de mecanismos radicales. Las barreras de baja activación favorecen los productos de cicloadición [4+2] y [2+2], controlando la distribución del producto final.

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