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The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
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Transferencia de hidruro intramolecular reversible entre el tántalo y un anillo aromático: un complejo

John Gavenonis1, T Don Tilley

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, California 94720-1460, USA.

Journal of the American Chemical Society
|July 18, 2002
PubMed
Resumen

Un complejo de tántalo reacciona con el hidrógeno para formar un complejo eta5-ciclohexadienilo. Esta reacción demuestra la inserción de un anillo de areno en un enlace metal-hidruro, un paso clave en la hidrogenación catalítica, y muestra reversibilidad.

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