Estereoquímica de síntesis de la formación de éter cíclico en la biosíntesis de 1,8-cineol catalizada por la síntesis

Mitchell L Wise1, Marek Urbansky, Gregory L Helms

  • 1Institute of Biological Chemistry, Washington State University, Pullman, Washington 99164, USA.

Resumen

Este estudio revela el mecanismo único de la 1,8-cineol sintasa. Utilizando sustratos etiquetados y RMN, los investigadores aclararon la vía de protonación-ciclización sin-facial intramolecular.

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