Un nuevo tipo de reacción catalítica en tándem de 1,4-adición-aldol que procede a través de un intermediario de

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Updated: Aug 8, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

Kazuhiro Yoshida1, Masamichi Ogasawara, Tamio Hayashi

  • 1Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

Journal of the American Chemical Society
|September 13, 2002
PubMed
Resumen

Este estudio introduce una reacción en tándem de 1,4-adición-aldol catalizada por el rodio utilizando 9-arilo-9-borabiciclo[3.3.1]nonanes. El proceso produce eficientemente productos sinselectivos a partir de cetonas y aldehídos insaturados.

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