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Racionalización de los efectos anómalos no lineales en la alquilación de los benzaldehidratos sustituidos

Frederic Buono1, Patrick J Walsh, Donna G Blackmond

  • 1Department of Chemistry, University of Hull, Hull HU6 7RX United Kingdom.

Journal of the American Chemical Society
|November 15, 2002
PubMed
Resumen

Los efectos no lineales anómalos en las reacciones de alquilación fueron explicados por un modelo modificado de Noyori. La partición del catalizador entre las formas monoméricas y diméricas, influenciada por las propiedades del sustrato, es clave.

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