Reacción del cloruro de vinilo con los catalizadores de polimerización de las olefinas de metales de transición

Stephen R Foley1, Robert A Stockland, Han Shen

  • 1Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60037, USA.

Resumen

La polimerización del cloruro de vinilo (VC) se ve obstaculizada por la rápida eliminación de beta-cloro de los complejos metálicos, lo que impide el crecimiento de la cadena. Esta eliminación de beta-Cl es el principal obstáculo para la polimerización de inserción de VC catalizado por metal.

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