Jove
Visualize
Contáctanos

Videos de Conceptos Relacionados

Surface Tension, Capillary Action, and Viscosity02:57

Surface Tension, Capillary Action, and Viscosity

Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
Complexation Equilibria: The Chelate Effect01:19

Complexation Equilibria: The Chelate Effect

In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
Surface Tension and Surface Energy01:16

Surface Tension and Surface Energy

When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Surface Tension01:24

Surface Tension

Surface tension is defined as the force per unit length (γ) acting along the surface of a liquid. It arises due to strong intermolecular forces of attraction. A molecule located inside the bulk of the liquid is surrounded by other molecules and experiences equal forces in all directions. However, a molecule at the surface experiences unbalanced forces because there are more neighboring molecules below than above. This creates a net inward force that pulls surface molecules toward the interior,...
Heterogeneous Catalysis01:22

Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
Surface Active Agents01:27

Surface Active Agents

Surfactants, named for their behavior at interfaces, positively adsorb at the interfaces of two phases, reducing interfacial tension. Their versatility as emulsifiers, detergents, and foaming agents stems from this ability. Surfactants, often termed amphiphiles, share the property of amphipathy, with molecules having both hydrophilic and hydrophobic portions. The hydrophilic part is called the head, and the hydrophobic part, including an elongated alkyl substituent, forms the tail.Surfactants...

También podría leer

Artículos Relacionados

Artículos vinculados a este trabajo por autores compartidos, revista y gráfico de citas.

Ordenar por
Same author

Author Correction: Hidden states and dynamics of fractional fillings in twisted MoTe<sub>2</sub> bilayers.

Nature·2026
Same author

Observation of coherent ferron emission and propagation.

Nature materials·2026
Same author

Roadmap for Photonics with 2D Materials.

ACS photonics·2025
Same author

Hidden states and dynamics of fractional fillings in twisted MoTe<sub>2</sub> bilayers.

Nature·2025
Same author

Time-domain signatures of distinct correlated insulators in a moiré superlattice.

Nature communications·2025
Same author

Optical spin hall effect in exciton-polariton condensates in lead halide perovskite microcavities.

The Journal of chemical physics·2024
JoVE
x logofacebook logolinkedin logoyoutube logo
ACERCA DE JoVE
Visión GeneralLiderazgoBlogCentro de Ayuda JoVE
AUTORES
Proceso de PublicaciónConsejo EditorialAlcance y PolíticasRevisión por ParesPreguntas FrecuentesEnviar
BIBLIOTECARIOS
TestimoniosSuscripcionesAccesoRecursosConsejo Asesor de BibliotecasPreguntas Frecuentes
INVESTIGACIÓN
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchivo
EDUCACIÓN
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualCentro de Recursos para ProfesoresSitio de Profesores
Términos y Condiciones de Uso
Política de Privacidad
Políticas

Video Experimental Relacionado

Updated: Jul 12, 2026

The Evolution of Silica Nanoparticle-polyester Coatings on Surfaces Exposed to Sunlight
10:27

The Evolution of Silica Nanoparticle-polyester Coatings on Surfaces Exposed to Sunlight

Published on: October 11, 2016

El efecto de quelato superficial es el efecto de quelato superficial.

Ryan C Major1, X-Y Zhu

  • 1Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, USA.

Journal of the American Chemical Society
|July 10, 2003
PubMed
Resumen

Los investigadores encontraron un fuerte efecto quelante superficial cuando los iones de cobre (Cu2+) se adsorben en una monocapa autoensamblada de ácido 16-mercaptohexadecanoico (MHA). Esta quelación superficial es significativamente más efectiva que en solución, lo que pone de relieve la importancia de la disposición de los ligandos.

Más Videos Relacionados

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance
11:47

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance

Published on: July 4, 2017

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

Videos de Experimentos Relacionados

Last Updated: Jul 12, 2026

The Evolution of Silica Nanoparticle-polyester Coatings on Surfaces Exposed to Sunlight
10:27

The Evolution of Silica Nanoparticle-polyester Coatings on Surfaces Exposed to Sunlight

Published on: October 11, 2016

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance
11:47

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance

Published on: July 4, 2017

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

Área de la Ciencia:

  • Química de las superficies.
  • Coordinación Química de la Coordinación
  • Ciencia de los materiales Ciencia de los materiales.

Sus antecedentes:

  • La quelación implica la unión de iones metálicos a los ligandos, formando anillos estables.
  • Los ligandos unidos a la superficie pueden exhibir propiedades de unión únicas en comparación con las moléculas libres.
  • La comprensión de las interacciones metal-ligando en superficies es crucial para diversas aplicaciones.

Objetivo del estudio:

  • Para establecer y cuantificar el efecto quelante superficial en un sistema modelo.
  • Para comparar la afinidad de unión de Cu2+ a un ligando unido a la superficie frente a los ligandos de la fase de solución.
  • Para investigar la influencia de una matriz bidimensional de ligandos en la quelación.

Principales métodos:

  • Adsorción de Cu2+ en una monocapa autoensamblada (SAM) de ácido 16-mercaptohexadecanoico (MHA) en una superficie de oro.
  • Comparación de las constantes de formación de Cu2+ con MHA en la superficie frente a los ácidos succínico y glutárico en solución acuosa.
  • Utilizando métodos establecidos para cuantificar las constantes vinculantes.

Principales resultados:

  • Se observó un efecto quelante superficial significativo para la adsorción de Cu2+ en el SAM MHA.
  • La constante de formación para el complejo superficial Cu2+-MHA fue sustancialmente mayor que para Cu2+ con ácido succínico o glutárico.
  • La unión mejorada se atribuye a la disposición organizada y bidimensional de los ligandos MHA en la superficie de oro.

Conclusiones:

  • El estudio demuestra un efecto quelante superficial generalizable para la adsorción de iones metálicos en superficies moleculares.
  • La efectividad de la quelación superficial depende en gran medida de la funcionalidad química y la organización estructural de la monocapa.
  • Este hallazgo tiene implicaciones para el diseño de superficies con propiedades de unión de metales a medida.