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Updated: Jul 11, 2026

A Toolkit to Enable Hydrocarbon Conversion in Aqueous Environments
20:28

A Toolkit to Enable Hydrocarbon Conversion in Aqueous Environments

Published on: October 2, 2012

La activación de enlaces C-H aromáticos vs alifáticos por el rodio (I) en función de las interacciones agósticas:

Boris Rybtchinski1, Revital Cohen, Yehoshoa Ben-David

  • 1Department of Organic Chemistry, The Weizmann Institute of Science, 76100 Rehovot, Israel.

Journal of the American Chemical Society
|September 4, 2003
PubMed
Resumen

Este estudio revela cómo diferentes ligandos fosfanos influyen en la activación C-H catalizada por el rodio y en las reacciones de intercambio H/D. El ligando aril-PC permite un intercambio H/D eficiente, a diferencia del ligando benzil-PC, debido a los distintos mecanismos de activación de enlaces C-H.

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