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Updated: Jul 21, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

Adición selectiva al iridio de enlaces arilo C-H ortho a grupos de coordinación. No es quelación asistida

Xiawei Zhang1, Mira Kanzelberger, Thomas J Emge

  • 1Department of Chemistry, Rutgers-The State University of New Jersey, Piscataway, New Jersey 08854, USA.

Journal of the American Chemical Society
|October 14, 2004
PubMed
Resumen

Los complejos de iridio ligados con pinza reaccionan con nitrobenzeno y acetofenona, formando productos quelados O,C a través de la adición de enlaces arilo C-H. Esta reacción ocurre sin la coordinación inicial del grupo funcional, lo que desafía las suposiciones anteriores sobre los mecanismos de activación C-H.

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