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Updated: Jul 5, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
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Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

Reactividad de la tirosinasa en un complejo modelo: un mecanismo de hidroxilación alternativo

Liviu M Mirica1, Michael Vance, Deanne Jackson Rudd

  • 1Department of Chemistry, Stanford University, CA 94305, USA.

Science (New York, N.Y.)
|June 25, 2005
PubMed
Resumen

Los investigadores sintetizaron un complejo de cobre que imita la tirosinasa, lo que permite una rápida hidroxilación del fenol. Este estudio revela un nuevo mecanismo que involucra la escisión secuencial de enlaces O-O y la formación de enlaces C-O en reacciones catalizadas por cobre.

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