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Propiedades únicas de absorción química de CO del hexámero de oro: Au6(CO) n- (n = 0-3)

Hua-Jin Zhai1, Boggavarapu Kiran, Bing Dai

  • 1Department of Physics, Washington State University, 2710 University Drive, Richland, Washington 99352, USA.

Journal of the American Chemical Society
|August 25, 2005
PubMed
Resumen

La quimiosorbción de monóxido de carbono (CO) en los racimos de oro hexámero (Au) es inusual, mostrando un efecto mínimo en las energías de unión de electrones. Este comportamiento se explica por la unión de CO a los sitios del ápice, sin afectar el orbital molecular desocupado más bajo del cúmulo.

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