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Síntesis, resolución y reacciones aldólicas de un complejo ácido de Lewis plano-quiral

Shih-Yuan Liu1, Ivory D Hills, Gregory C Fu

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.

Journal of the American Chemical Society
|November 3, 2005
PubMed
Resumen

Los investigadores sintetizaron un nuevo complejo de ácido de Lewis plano-quiral para las reacciones asimétricas de Mukaiyama aldol. Este catalizador logra una alta estereoselectividad, alineándose con su diseño como aceptor dual de sigma y pi.

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