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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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La activación de enlaces C-H intermoleculares es promovida por una alquilidina de titanio

Brad C Bailey1, Hongjun Fan, Erich W Baum

  • 1Department of Chemistry, Molecular Structure Center and School of Informatics, Indiana University, Bloomington, Indiana 47405, USA.

Journal of the American Chemical Society
|November 17, 2005
PubMed
Resumen

Este estudio revela que un complejo de alquilidina de titanio transitorio agrega fácilmente enlaces C-H a través de una vía de alquilidina. La abstracción de alfa-hidrógeno se identifica como el paso que determina la velocidad en esta química del titanio.

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