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Construcción de anillo de ocho miembros por [4 + 2 + 2] anulación que implica la eliminación de beta-carbono

Masahiro Murakami1, Shinji Ashida, Takanori Matsuda

  • 1Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan. murakami@sbchem.kyoto-u.ac.jp

Journal of the American Chemical Society
|February 16, 2006
PubMed
Resumen

Los catalizadores de níquel ((0) facilitan una nueva anulación [4 + 2 + 2] entre las ciclobutanonas y las diinas. Esta reacción sintetiza eficientemente cetonas ciclicas de anillo de ocho miembros, ofreciendo una nueva ruta a los núcleos de ciclooctadienona.

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