El control inducido por ligandos de C-H frente a las reacciones alifáticas de migración C-C de los carbenoides Rh

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Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source
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Published on: August 17, 2018

Maxime Vitale1, Thomas Lecourt, Chris G Sheldon

  • 1School of Chemistry, University of Bristol, Cantock's Close, UK.

Journal of the American Chemical Society
|February 24, 2006
PubMed
Resumen

Los diazocompuestos alfa-siliados estables reaccionan con catalizadores de rodio para formar éteres alfa-sililo-sililo-enol. La elección del catalizador dicta si se produce la migración de enlaces C-H o C-C, dando lugar a diferentes productos.

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