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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

La alfa-ariación enantioselectiva y catalizada por el paladio de la N-Boc-pirrolidina

Kevin R Campos1, Artis Klapars, Jacob H Waldman

  • 1Department of Process Research, Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065, USA. kevin_campos@merck.com

Journal of the American Chemical Society
|March 16, 2006
PubMed
Resumen

Este estudio introduce una nueva alfa-ariación enantioselectiva catalizada por el paladio de N-Boc-pirrolidina. El método sintetiza de manera eficiente las pirrolidinas quirales 2-arilo-N-Boc con una alta relación enantiomérica (er).

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