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[3,3]-reorganizaciones de los ylidos de fosfonio

Marcelle L Ferguson1, Todd D Senecal, Todd M Groendyke

  • 1Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.

Journal of the American Chemical Society
|April 6, 2006
PubMed
Resumen

Un nuevo método genera eficientemente ylidos de fosfonio alilico a partir de alcoholes alilicos, carbenos y clorofosfitos. Estos ylidos se someten a una reorganización [3,3] para producir valiosos fosfonatos homoalílicos.

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