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Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR
10:54

Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR

Published on: February 23, 2016

Difusión local en soluciones paramagnéticas por relajometría de RMN a una frecuencia.

Andrea Melchior1, Pascal H Fries

  • 1Laboratoire de Reconnaissance Ionique, Service de Chimie Inorganique et Biologique, UMR-E 3 CEA-UJF, CEA/DSM/Département de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, F-38054 Grenoble Cédex 9, France.

Journal of the American Chemical Society
|June 8, 2006
PubMed
Resumen

Este estudio introduce un método novedoso y no invasivo para medir el coeficiente de difusión relativo (D) de las moléculas paramagnéticas y diamagnéticas utilizando tiempos de relajación de resonancia magnética nuclear (RMN). La técnica ofrece un enfoque fácil de usar para los instrumentos estándar de RMN.

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