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Updated: Aug 8, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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Alilación catalítica enantioselectiva de las cetoiminas

Reiko Wada1, Tomoyuki Shibuguchi, Sae Makino

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|June 8, 2006
PubMed
Resumen

Un nuevo método catalítico permite la alilación de las cetoiminas utilizando fluoruro de cobre (CuF) y el éster de pinacol del ácido alilborónico. Este enfoque logra una alta enantioselectividad, allanando el camino para la síntesis asimétrica de compuestos valiosos.

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