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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

Estudios de DFT sobre el mecanismo de la dearomatización alilativa catalizada por el paladio

Alireza Ariafard1, Zhenyang Lin

  • 1Department of Chemistry, Faculty of Science, Central Tehran Branch, Islamic Azad University, Felestin Square, Tehran, Iran.

Journal of the American Chemical Society
|September 28, 2006
PubMed
Resumen

Los cálculos de la teoría funcional de la densidad revelaron el mecanismo del acoplamiento bencilo/alilo catalizado por el paladio. El intermediario (eta(3)-bencilo) ((eta(1)-alilo) (Pd(PH(3)) impulsa la formación de productos aromatizados a través de la eliminación reductora.

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