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Updated: Jul 16, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Inserción de oxígeno molecular en un enlace palladio-hidruro: evidencia computacional para dos vías casi

Brian V Popp1, Shannon S Stahl

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA. bpopp@chem.wisc.edu

Journal of the American Chemical Society
|March 21, 2007
PubMed
Resumen

Las reacciones de oxidación aeróbica catalizadas por paladio pueden implicar múltiples vías para la reoxidación del catalizador. Los cálculos de DFT muestran que la abstracción del átomo de hidrógeno y la eliminación reductiva son las rutas energéticamente preferidas para que el hidruro de paladio reaccione con el oxígeno.

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