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Updated: Jul 14, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Activación de complejos de hidruro metálico por los grupos tri-ter-butilofosfina-platino y -palladio

Richard D Adams1, Burjor Captain, Eszter Trufan

  • 1Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, USA. Adams@mail.chem.sc.edu

Journal of the American Chemical Society
|May 29, 2007
PubMed
Resumen

Los hidruros metálicos HM(CO) 4SnPh3, donde M es Osmio (Os) o Rutenio (Ru), reaccionan con fenilacetileno (PhC2H) en presencia de complejos de platino o paladio. Esta reacción conduce a la inserción de fenilacetileno en el enlace metal-hidruro, formando nuevos compuestos organometálicos.

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