Fácil y selectiva activación alifática del enlace C-H a temperatura ambiente iniciada por Cp*W(NO) ((CH2CMe3) ((eta

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Updated: Jul 7, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

Jenkins Y K Tsang1, Miriam S A Buschhaus, Peter M Graham

  • 1Department of Chemistry, The University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z1.

Journal of the American Chemical Society
|February 21, 2008
PubMed
Resumen

Este estudio detalla la termólisis de un complejo de tungsteno, formando un intermediario que activa los enlaces C-H en alcanos e hidrocarburos gaseosos. También se somete a reacciones de acoplamiento con moléculas insaturadas, con la activación C-H dominante en los alquenos estéricamente obstaculizados.

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