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Elucidación estructural, espectroscópica y teórica de un auxiliar de tipo pinza redox activo aplicado en catálisis

Debashis Adhikari1, Susanne Mossin, Falguni Basuli

  • 1Department of Chemistry and the Molecular Structure Center, Indiana University, Bloomington, Indiana 47405, USA.

Journal of the American Chemical Society
|February 28, 2008
PubMed
Resumen

Los ligandos de pinza son robustos andamios en la química organometálica. Este estudio revela que un ligando específico de pinza PNP unido al níquel exhibe un comportamiento redox no inocente, capaz de albergar un agujero de electrones.

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