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KOH en polvo en DMSO: una base eficiente para la ciclización asimétrica a través de la memoria de la quiralidad a

Takeo Kawabata1, Katsuhiko Moriyama, Shimpei Kawakami

  • 1Institute for Chemical Research, Kyoto University Uji, Kyoto 611- 0011, Japan. kawabata@scl.kyoto-u.ac.jp

Journal of the American Chemical Society
|February 29, 2008
PubMed
Resumen

El hidróxido de potasio en polvo en DMSO permite la formación de enlaces C-C altamente enantioselectivos a temperatura ambiente. Este método logra resultados superiores en comparación con las condiciones anidras tradicionales de baja temperatura para crear productos intermedios quirales enolados.

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