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Updated: Jul 5, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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Reactividad química de D3h C78 (metal) fullereno: cambios de regioselectividad inducidos por la encapsulación Sc3N

Sílvia Osuna1, Marcel Swart, Josep M Campanera

  • 1Institut de Química Computacional and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spain.

Journal of the American Chemical Society
|April 17, 2008
PubMed
Resumen

Encapsular un grupo de nitruro metálico dentro de un fullereno altera significativamente su reactividad exohedral. Las reacciones de Diels-Alder en metallofulerenos endoderales producen productos diferentes en comparación con los fulerenos libres debido a sitios de reacción alterados.

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