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Updated: Jul 5, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

Pruebas experimentales para el túnel de movimiento acoplado mejorado por enzimas / hidrógeno mecánico cuántico

Thomas C Wilde1, Grzegorz Blotny, Ralph M Pollack

  • 1Department of Chemistry and Biochemistry, University of Maryland Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250, USA.

Journal of the American Chemical Society
|April 23, 2008
PubMed
Resumen

Este estudio investigó el túnel de hidrógeno mecánico cuántico (HT) en reacciones enzimáticas y no enzimáticas. Los resultados muestran que la 3-oxo-Delta(5)-esteroide isomerasa (KSI) mejora la HT, contribuyendo a su aceleración de la velocidad catalítica.

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