Video Experimental Relacionado

Updated: Jul 5, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

La cicloadición intramolecular [3 + 2] catalizada por Rh ((I) de los enes trans-vinilciclopropano es cíclica

Lei Jiao1, Siyu Ye, Zhi-Xiang Yu

  • 1Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.

Journal of the American Chemical Society
|May 16, 2008
PubMed
Resumen

El vinilciclopropano (VCP) ahora puede actuar como un sintón de tres carbonos en cicloadiciones [3 + 2] catalizadas por Rh, formando carbociclos de cinco miembros. Esto contrasta con su uso típico como una unidad de cinco carbonos, lo que permite nuevas vías sintéticas.

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