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Updated: Jul 4, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

Síntesis de las azepinas por una anulación intermolecular [4 + 3] catalizada por oro

Nathan D Shapiro1, F Dean Toste

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|June 26, 2008
PubMed
Resumen

Los investigadores desarrollaron un nuevo método catalizado por oro para sintetizar azepinas. Esta reacción conveniente implica la anulación de los ésteres de propargilo y las iminas alfa, beta insaturadas, ofreciendo una valiosa ruta sintética.

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