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Updated: Jul 4, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

Una ciclización "anti-Baldwin" de 3 exo-dig: preparación de vinildeno ciclopropanos a partir de alquenos pobres en

Matthew J Campbell1, Patrick D Pohlhaus, Geanna Min

  • 1Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, USA.

Journal of the American Chemical Society
|June 28, 2008
PubMed
Resumen

Los carbaniones estabilizados ciclan sobre los haluros de propargilo a través de la sustitución de SN2', produciendo vinilideno ciclopropanos. Este método ofrece acceso a estructuras únicas de ciclopropano no alcanzables a través de reacciones tradicionales de carbenos.

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