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Updated: Jul 4, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

Ciclocondensación deshidrogenativa de aldehídos, alquinas y dialquilisilanes

Ryan D Baxter1, John Montgomery

  • 1Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA.

Journal of the American Chemical Society
|July 5, 2008
PubMed
Resumen

La catálisis del níquel permite una nueva reacción entre aldehídos, alquinas y silanos, formando anillos de cinco miembros. Este proceso utiliza dialquilosilanos como un equivalente de sileno, ofreciendo una nueva ruta sintética.

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