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Updated: Jun 30, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Identificación inequívoca de la aromaticidad de Möbius para las hexafirinas [28] sustituidas por meso-arilo

Jeyaraman Sankar1, Shigeki Mori, Shohei Saito

  • 1Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.

Journal of the American Chemical Society
|September 24, 2008
PubMed
Resumen

Las hexafirinas meso-arilo-sustituidas [28] exhiben conformaciones dinámicas de Möbius en solución, que pueden congelarse a bajas temperaturas. Este estudio confirma la aromaticidad estable de Möbius en las porfirinas expandidas de base libre, un avance significativo en la química macrocíclica.

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