Estrategia para emplear nucleófilos inestabilizados en alquilaciones alilicas asimétricas catalizadas por el paladio

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Updated: Jun 29, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

Barry M Trost1, David A Thaisrivongs

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA. bmtrost@stanford.edu

Journal of the American Chemical Society
|October 2, 2008
PubMed
Resumen

Este estudio introduce un nuevo método para el uso de aniones 2-metilpiridil inestables en alquilaciones alilicas asimétricas catalizadas por paladio (AAA). La estrategia desarrollada activa estos aniones, lo que permite su uso en reacciones AAA con alta selectividad.

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