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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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Síntesis y revisión de la estructura de la nakiterpiosina

Shuanhu Gao1, Qiaoling Wang, Chuo Chen

  • 1Department of Biochemistry, The University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, USA.

Journal of the American Chemical Society
|November 13, 2008
PubMed
Resumen

Los investigadores sintetizaron eficientemente la nakiterpiosina, un esteroide marino, revisando su estereoquímica. Las reacciones clave incluyeron el acoplamiento carbonilativo de Stille y la ciclización foto-Nazarov para el esqueleto completo.

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