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Updated: Jun 27, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

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Published on: August 16, 2018

Ciclización mediada por metales de éteres de arilo y glicidil bencilo: un escenario completo

Rocío Marcos1, Carles Rodríguez-Escrich, Clara I Herrerías

  • 1Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.

Journal of the American Chemical Society
|December 5, 2008
PubMed
Resumen

Los éteres de arilo y glicidil bencilo enantioméricamente puros ciclizan eficientemente a 3-cromanolos o tetrahidrobenzo [c] oxepina-4-ols utilizando hierro (III) bromuro / plata (I) triflato. Los catalizadores de oro son menos efectivos, lo que indica los mecanismos de reacción de Friedel-Crafts.

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