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Efectos de sustitución sobre la regioselectividad en la autooxidación de dienos no conjugados

Keri A Tallman1, Christopher L Rector, Ned A Porter

  • 1Department of Chemistry and Center in Molecular Toxicology, Vanderbilt University, Nashville, Tennessee 37235, USA.

Journal of the American Chemical Society
|April 1, 2009
PubMed
Resumen

La concentración de alfa-tocoferol y la estructura de dieno influyen en los productos de oxidación. Los sustituyentes más grandes en dienes favorecen las formaciones específicas de hidroperoxido durante la oxidación de radicales libres.

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