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Probando el mecanismo de la captura de electrones y la disociación de la transferencia de electrones utilizando

Chang Ho Sohn1, Cheol K Chung, Sheng Yin

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|April 1, 2009
PubMed
Resumen

Se investigaron los mecanismos de disociación por captura de electrones (ECD) y disociación por transferencia de electrones (ETD) utilizando péptidos sintonizados por afinidad electrónica (EA). Los depredadores de electrones de alta EA inhiben la fragmentación mediante la formación de radicales estables intermedios a través de la transferencia de protones, alterando las vías estándar de ECD/ETD.

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