Acceso controlado por ligandos a [4 + 2] y [4 + 3] cicloadiciones en reacciones catalizadas por oro de aleno-dienos

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Updated: Jun 23, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

Pablo Mauleón1, Rachel M Zeldin, Ana Z González

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|April 22, 2009
PubMed
Resumen

Los catalizadores Gold (I) permiten las cicloadiciones selectivas aleno-dieno. La elección del ligando dicta la vía de reacción, dando como resultado productos de cicloadición [4 + 2] como los alquilidenciclohexenos o productos de cicloadición [4 + 3] como los cicloheptadienos.

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