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Published on: February 7, 2019

IBiox[(-)-mentilo]: un ligando NHC quiral estérico y exigente

Sebastian Würtz1, Claudia Lohre, Roland Fröhlich

  • 1Organisch-Chemisches Institut der Westfälischen Wilhelms-Universität Munster, Corrensstrasse 40, 48149 Münster, Germany.

Journal of the American Chemical Society
|June 3, 2009
PubMed
Resumen

Se sintetizó un nuevo ligando quiral del NHC, el IBiox[(-)-mentilo. Este ligando estéricamente exigente permite alfa-arilaciones altamente enantioselectivas y la formación de oxíndolos, logrando hasta un 99% de exceso enantiomérico.

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