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Updated: Jun 22, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
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Published on: August 23, 2018

CO ayuda en el intercambio de ligandos de un catalizador de racemización de rutenio: identificación de un

Jenny B Aberg1, Jonas Nyhlén, Belén Martín-Matute

  • 1Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.

Journal of the American Chemical Society
|June 19, 2009
PubMed
Resumen

Los investigadores identificaron un intermediario acilo clave durante la activación de eta(5)-(Ph(5)Cp)Ru(CO)(2)Cl utilizando tert-butóxido. Este descubrimiento confirma que el intercambio de ligandos se produce a través de la asistencia de monóxido de carbono (CO), que implica un ataque nucleófilo a un ligando de CO.

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